Mixed-modifier effect in alkaline earth metaphosphate glasses
نویسندگان
چکیده
منابع مشابه
Modifier Interaction and Mixed-Alkali Effect in Bond Constraint Theory Applied to Ternary Alkali Metaphosphate Glasses
Introducing an interaction parameter γ, we implement modifier interaction and the mixed-alkali effect into bond constraint theory and apply this extension for simplistic property prediction on ternary phosphate glasses. The severity of the mixed-alkali effect results from the interplay of two simultaneous contributions: bond constraints on the modifier species soften and stiffen with decreasing...
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In this work, mixed alkali metaphosphate glasses based on K-Na, Rb-Na, Rb-Li, Cs-Na and Cs-Li combinations were studied by differential scanning calorimetry (DSC), complex impedance spectroscopy, and Raman spectroscopy. DSC analyses show that both the glass transition (Tg) and melting temperatures (Tm) exhibit a clear mixed-ion effect. The ionic conductivity shows a strong mixed-ion effect and ...
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The structure of the glass forming system (V2O5)x – (Na2O · P2O5)(1–x), (x = 0–0.4), has been investigated using Raman spectroscopy. The stretching vibrations of various phosphate groups, connected to phosphorus or vanadium atoms, have been assigned. Variation of the composition leads to structural changes where the sodium metaphosphate -P–O–P-chains break and then reconnect with the oxovanadiu...
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‘?Si NMR spectroscopy provides important contributions to the understanding of silicate glass structure. as the resonance frequency is sensitive to several aspects of the local chemical environment (including intertetrahedral bond angles. bond distances. and number of bridging oxygens per silicon atom). New data on a series of binary alkali and alkaline earth glasses are presented which highlig...
متن کاملDynamic light scattering in mixed alkali metaphosphate glass forming liquids.
We report the first ever photon correlation spectroscopy performed on single alkali and mixed alkali metaphosphate glasses at refractory temperatures above the glass transition. We find not only a significant decrease in the glass transition temperature but also a decrease in fragility for the mixed alkali composition as compared with the single akali glasses. We argue that structural relaxatio...
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ژورنال
عنوان ژورنال: Journal of Non-Crystalline Solids
سال: 2018
ISSN: 0022-3093
DOI: 10.1016/j.jnoncrysol.2017.11.041